I agree with the plan
rgray described. The extreme speed difference of SSDs makes the start up process (for the OS and/or an app) well worth the extra cost for many people. This method works because the SSD is mainly used for nothing but reading; it is accessed to install the OS/app as opposed to writing data to it. SSDs have two basic types and you may not even know which you are getting when you buy; try to find out Single Layer Cell (SLC) types are longer lasting than Multi-Layer Cell (MLC) types. Worse, as new devices come out with higher and higher GB sizes, their lifetimes are actually getting shorter; to increase the GBs, the usual method is to make smaller cells, smaller cells means more problems in maintaining the state of the bits, voltage leakage, etc. Mind you, your SSD will no doubt outlast your laptop! And it will probably outlast the new HD you're thinking about installing in place of the optical drive. But SSDs should be used for reading as opposed to writing to make them last as long as possible.
Here are a few links for your enjoyment:
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SSD Myths and Legends, Storage Research.com>
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SSD vs HDD - life span, Tom's Hardware.com> Many additional links in this forum
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How Much I Write to Disk Per Day, interesting and comforting info and a link to the next site/source>
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Samsung SSD 840 (250GB) Review>