The Macbook Pro also prefers matched sticks, but I actually doubt you will notice much if you install that 512 stick. If she is using ram intensive applications like photoshop, the added benefit of the extra half gig should outweigh any performance lost by not having matched sticks. In fact, by having a single 1 gig stick in there instead of a pair of 512's you are already lacking the slight benefit you could have realized with a matched pair.
I currently have two 1 gig sticks in my Macbook Pro, but I used to have a single 1 gig stick. When I added the second, I did not really notice anything until I started up parallels. having the extra ram allowed me to run both OS X and XP with virtually no performance loss. When I tried this with one gig, I would get a lot of lag.
Steve