GR,
As far as I know, your internal ATA/66 Bus will only support two drives, so there's no way that third HD is going to be recognized. That power and connector underneath the DVD drive is for a ZIP Drive, I believe, or may work on another optical drive, but will not support or recognize another HD.
You'll have to get an ATA controller card to put a third ATA HD in. I believe that most host controllers use cable select. And most ATA controllers will let you connect up to four drives, and are bootable under both OS 9x and OS 10x. If you need a specific recommendation, either Krissel or myself would be happy to help you.
I have both an ATA controller and a SATA controller card in my PCI slots on my DA, fyi.
Here is an ATA Card which I have in my DA on closeout from OWC:
ACARD 6280ATA host cards are becoming an endangered species, so act fast if you want one.
And here is the same SATA card that both Krissel and I have, but labeled from a different company:
Sonnet Tempo SATA cardHTH,
Chris